Radical-ion-pair reactions are the biochemical equivalent of the optical double-slit experiment.
نویسنده
چکیده
Radical-ion-pair reactions were recently shown to represent a rich biophysical laboratory for the application of quantum measurement theory methods and concepts. Here we show that radical-ion-pair reactions essentially form a nonlinear biochemical double-slit interferometer. Quantum coherence effects are visible when "which-path" information is limited, and the incoherent limit is approached when measurement-induced decoherence sets in. Based on this analogy with the optical double-slit experiment we derive and elaborate on the fundamental master equation of spin-selective radical-ion-pair reactions that covers the continuous range from complete incoherence to maximum singlet-triplet coherence.
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عنوان ژورنال:
- Physical review. E, Statistical, nonlinear, and soft matter physics
دوره 83 5 Pt 2 شماره
صفحات -
تاریخ انتشار 2011